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Benzene facts for kids

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Model of a molecule of benzene. Carbon atoms are shown as black and hydrogen as white.
Stamps of Germany (BRD) 1964, MiNr 440
In 1964, the German postal service issued a stamp in commemoration of 100 years discovery of Benzene

Benzene, also known as benzol, is an organic chemical compound with the formula C6H6. It is a colorless and flammable liquid with a sweet smell. Benzene molecules are a ring of six carbon atoms that are each bonded to one hydrogen atom. It is an aromatic compound, meaning the ring has alternating double bonds.

Benzene is carcinogenic, which means it can cause cancer. It has many real-world uses. It is used as an additive in gasoline, plastics, synthetic rubber, dyes and it is an industrial solvent, which means it can dissolve many other chemical molecules. Benzene is also a natural part of crude oil and is therefore present in gasoline. Many medicines contain parts made from benzene.


Benzene has special properties called aromaticity. All six carbon atoms in the ring are on the same flat plane. To account for all the bonds on a six carbon ring, there must be alternating double carbon bonds (Conjugated system):

Benzene Representations
The various representations of benzene

If benzene had three double bonds, three sides of its ring would be shorter than the other three sides. X-ray diffraction shows that all of six carbon-carbon bonds in benzene are of the same length of 140 picometres (pm). The C–C bond lengths are greater than a double bond (135 pm) but shorter than a single bond (147 pm).. One representation is that the structure exists as a superposition of so-called resonance structures, rather than either form individually. (In other words, the molecule's double bonds switch quickly between pairs of carbon atoms.) The delocalization of electrons is one explanation for the thermodynamic stability of benzene and related aromatic compounds. It is likely that this stability contributes to the peculiar molecular and chemical properties known as aromaticity. To indicate the delocalized nature of the bonding, benzene is often depicted with a circle inside a hexagonal arrangement of carbon atoms.

As is common in organic chemistry, the carbon atoms in the diagram above have been left unlabeled. Realizing each carbon has 2p electrons, each carbon donates an electron into the delocalized ring above and below the benzene ring. It is the overlap of p-orbitals both above and below the ring that produces the pi clouds.

In 1986, some chemists disputed the delocalized view of benzene in an article published in the journal Nature. They showed that the electrons in benzene are almost certainly localized to particular carbon atoms. They showed the aromatic properties of benzene come from spin coupling rather than electron delocalization. Other scientists wrote articles to support this view in Nature in 1987. But, chemists are slow to switch from the delocalized electrons view.

Derivatives of benzene occur sufficiently often as a component of organic molecules that there is a Unicode symbol in the Miscellaneous Technical block with the code U+232C () to represent it with three double bonds, and U+23E3 () for a delocalized version.

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Kids robot.svg In Spanish: Benceno para niños

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