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Potassium hydroxide
Potassium-hydroxide-xtal-3D-vdW.png
Potassium hydroxide.jpg
IUPAC name Potassium hydroxide
Other names
  • Caustic potash
  • Lye
  • Potash lye
  • Potassia
  • Potassium hydrate
  • KOH
Identifiers
CAS number 1310-58-3
PubChem 14797
EC number 215-181-3
ChEBI CHEBI:32035
RTECS number TT2100000
SMILES [K+].[OH-]
Properties
Molecular formula
Molar mass 0 g mol-1
Appearance white solid, deliquescent
Odor odorless
Density 2.044 g/cm3 (20 °C)
2.12 g/cm3 (25 °C)
Melting point
Boiling point
85 g/100 mL (−23.2 °C)
97 g/100 mL (0 °C)
121 g/100 mL (25 °C)
138.3 g/100 mL (50 °C)
162.9 g/100 mL (100 °C)
Solubility soluble in alcohol, glycerol
insoluble in ether, liquid ammonia
Solubility in methanol 55 g/100 g (28 °C)
Solubility in isopropanol ~14 g / 100 g (28 °C)
Acidity (pKa) 14.7
−22.0·10−6 cm3/mol
Refractive index (nD) 1.409 (20 °C)
Thermochemistry
Std enthalpy of
formation ΔfHo298
−425.8 kJ/mol
Standard molar
entropy So298
79.32 J/mol·K
Specific heat capacity, C 65.87 J/mol·K
Hazards
NFPA 704

NFPA 704.svg

0
3
1
 
Flash point nonflammable
U.S. Permissible
exposure limit (PEL)
none
Related compounds
Other anions Potassium hydrosulfide
Potassium amide
Other cations Lithium hydroxide
Sodium hydroxide
Rubidium hydroxide
Caesium hydroxide
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Potassium hydroxide is a white, solid inorganic compound made of potassium and hydroxide. People also call it caustic potash or potassium lye. Like sodium hydroxide, it is a very strong base. It can quickly neutralize acids and dissolve in water. When mixed with water, it gives off lots of heat in an exothermic reaction.

What Makes Potassium Hydroxide Special?

Potassium hydroxide has a special crystal pattern like NaCl salt. It is hygroscopic, which means it pulls moisture right out of the air. It dissolves easily in liquids, including water, methanol, and alcohol. Because it loves water so much, scientists use it as a desiccant to dry out other chemicals.

Making Soft Soaps and Cleaners

When potassium hydroxide reacts with greasy animal fat, it undergoes saponification. This process turns oils into soft soaps and glycerol. These special soaps dissolve easily in water, making them great for liquid body washes. It is also used to make powerful cleaning solutions that help disinfect surfaces.

Powering Batteries and Electronics

LeakedBattery 2701a
Potassium carbonate, formed from the hydroxide solution leaking from an alkaline battery

This chemical is a key ingredient in portable energy. An aqueous mix acts as an electrolyte inside many alkaline batteries. It carries electric charges very well in nickel-cadmium cells and nickel-metal hydride batteries. Car makers even use it inside hybrid cars like the Toyota Prius. High-purity versions help etch tiny parts on computer chips and solar cells.

Helping Plants and Making Food

Factories react potassium hydroxide with acids to make potassium phosphate, which provides nutrients in fertilizers. In the food world, it is known as E525 and approved by the FDA. Food makers use it to control acidity and help process tasty foods like cocoa and olives.

Studying Fungi and Nature

Scientists use a drop of this liquid to study wild mushrooms. The liquid reacts with certain fungi like gilled mushrooms, boletes, and polypores, causing them to change color. This handy test helps researchers identify different kinds of mushrooms and lichens quickly.

Staying Safe Around Caustic Potash

Potassium hydroxide spillage
Potassium hydroxide spillage, stained red by phenolphthalein

Potassium hydroxide is very caustic and can cause a bad burn if touched. It reacts with natural skin oils, making it feel slippery before hurting skin tissue. It can be made harmless when it is neutralised with an acid to create a safe salt.

See also

Kids robot.svg In Spanish: Hidróxido de potasio para niños

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