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Rubidium, 37Rb
Rb5.JPG
Rubidium
Pronunciation /ruːˈbɪdiəm/ ​(roo-BID-ee-əm)
Appearance grey white
Standard atomic weight Ar, std(Rb) 85.4678(3)
Rubidium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
K
↑
Rb
↓
Cs
krypton ← rubidium → strontium
Atomic number (Z) 37
Group group 1: hydrogen and alkali metals
Period period 5
Block   s
Electron configuration [Kr] 5s1
Electrons per shell 2, 8, 18, 8, 1
Physical properties
Phase at STP solid
Melting point 312.45 K ​(39.30 °C, ​102.74 °F)
Boiling point 961 K ​(688 °C, ​1270 °F)
Density when liquid (at m.p.) 1.46 g/cm3
Triple point 312.41 K, ​? kPa
Critical point 2093 K, 16 MPa (extrapolated)
Heat of fusion 2.19 kJ/mol
Heat of vaporization 69 kJ/mol
Molar heat capacity 31.060 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 434 486 552 641 769 958
Atomic properties
Oxidation states −1, +1 (a strongly basic oxide)
Electronegativity Pauling scale: 0.82
Ionization energies
  • 1st: 403 kJ/mol
  • 2nd: 2632.1 kJ/mol
  • 3rd: 3859.4 kJ/mol
Atomic radius empirical: 248 pm
Covalent radius 220±9 pm
Van der Waals radius 303 pm
Color lines in a spectral range
Spectral lines of rubidium
Other properties
Natural occurrence primordial
Crystal structure ​body-centered cubic (bcc)
Body-centered cubic crystal structure for rubidium
Speed of sound thin rod 1300 m/s (at 20 °C)
Thermal conductivity 58.2 W/(m⋅K)
Electrical resistivity 128 nΩ⋅m (at 20 °C)
Magnetic ordering paramagnetic
Molar magnetic susceptibility +17.0×10−6 cm3/mol (303 K)
Young's modulus 2.4 GPa
Bulk modulus 2.5 GPa
Mohs hardness 0.3
Brinell hardness 0.216 MPa
CAS Number 7440-17-7
History
Naming from Latin rubidus, 'deep red', for the color of its emission spectrum
Discovery Gustav Kirchhoff and Robert Bunsen (1861)
First isolation George de Hevesy
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct

Rubidium is a soft, silvery-white chemical element. On the periodic table, it has the symbol Rb and the atomic number 37. It belongs to a special family of elements called the alkali metal group. This means it shares many traits with neighbors like potassium and caesium. Rubidium is very soft, like butter, and can be easily cut with a butter knife. It is also quite heavy compared to other metals in its group. In fact, it is the first alkali metal that sinks in water.

Natural rubidium found on Earth contains two main kinds of isotopes. About 72% is completely stable, while 28% is slightly radioactive. This natural radioactive form takes an amazingly long time to break down. Its half-life is about 48.8 billion years. That is more than three times older than the whole age of the universe! Because of this, scientists can safely study natural rubidium without worrying about high levels of radiation.

Amazing Features of Rubidium Metal

Physical Properties and Appearance

RbH
Partially molten rubidium metal sealed inside an ampoule

Rubidium is a silvery-white metal with great flexibility, meaning scientists can easily bend it into thin wires. It melts at a fairly low temperature of 39.3 °C (102.7 °F). This means that on a very hot summer day, a piece of rubidium would begin to turn into a liquid!

Rubidium mixes well with other metals. It can form special mixtures called amalgams with mercury. It also creates an alloy when melted with gold, iron, caesium, sodium, or potassium. When chemists place rubidium in a flame during a flame test, it glows with a pretty violet or purple color. This glow looks very similar to the purple flame of potassium.

Chemical Reactions and Behavior

Rb&Cs crystals
Rubidium crystals (silvery) next to golden caesium crystals

Rubidium is an extremely reactive chemical element. It holds onto its outer electrons very loosely because of its low ionization energy. Because it gives up electrons so easily, it is considered highly electropositive.

When rubidium touches moisture, it reacts instantly and violently. It breaks down liquid into rubidium hydroxide and produces bubbly hydrogen gas. The reaction creates so much heat that the hydrogen gas can catch fire immediately! Rubidium can even burst into flames purely from touching normal air. Because of this extreme danger, chemists must store it inside sealed glass tubes or submerge it completely under dry mineral oil.

Useful Compounds

Rb9O2 cluster
A special cluster made of rubidium and oxygen atoms

When rubidium bonds with other elements, it forms helpful materials called compounds. One common example is Rubidium chloride, a salt that helps scientists study DNA inside living cells. Another compound is rubidium carbonate, which helps factories make special types of optical glass.

When rubidium meets oxygen, it creates different kinds of oxides, including a rare kind called a rubidium superoxide. Rubidium also bonds easily with elements from the halogen family. These reactions create salts such as rubidium fluoride, rubidium chloride, rubidium bromide, and rubidium iodide. Another compound, Rubidium silver iodide, carries electricity remarkably well at room temperature. Scientists use this high electrical conductiveness to build tiny, ultra-thin batteries.

How Scientists Discovered Rubidium

Kirchhoff Bunsen Roscoe
Gustav Kirchhoff and Robert Bunsen discovered rubidium using light analysis

Two famous German scientists, Robert Bunsen and Gustav Kirchhoff, discovered rubidium in 1861. They were studying a shiny mineral called lepidolite in their laboratory. To identify unknown materials, they used a brand-new scientific method called flame spectroscopy.

When they burned the mineral, their new tool, the spectroscope, split the light into separate bright bands. They spotted bright, deep red lines in the light pattern, known as an emission spectrum. These lines did not match any known substance on Earth. Bunsen and Kirchhoff realized they had found a brand-new element. They named it after the Latin word rubidus, which translates to "deep red".

Later on, Bunsen worked hard to isolate pure rubidium metal from minerals and mineral water. In 1995, modern physicists used rubidium atoms chilled by a laser to create a totally new state of matter called a Bose–Einstein condensate. This groundbreaking work earned scientists Eric Allin Cornell, Carl Edwin Wieman, and Wolfgang Ketterle the famous Nobel Prize in Physics in 2001.

Where Rubidium Is Found in Nature

Die Flammenfärbung des Rubidium
A flame test showing the bright color of burning rubidium

Rubidium is surprisingly common on our planet. Looking at the total abundance of elements in Earth's crust, rubidium ranks as the 23rd most common element. It is actually more plentiful than familiar metals like zinc or copper! However, it is spread out thinly across many rocks rather than gathered in large, pure lumps.

Small amounts of rubidium hide inside minerals such as carnallite, pollucite, and lepidolite. Earth also holds rubidium in the oceans. Natural Seawater contains about 125 micrograms of dissolved rubidium in every single liter of water.

Geologists also use rubidium to figure out how old ancient stones are. A natural isotope called rubidium-87 slowly turns into stable strontium over billions of years through beta decay. By measuring how much strontium has formed, scientists can calculate the age of rocks through rock dating techniques. This amazing method is called rubidium–strontium dating.

Modern Uses for Rubidium Today

USNO rubidium fountain
A rubidium fountain atomic clock used for high-precision timekeeping

Even though rubidium is tricky to handle, it does many helpful jobs in science and modern technology:

  • Ultra-precise clocks: Rubidium is a key part of portable atomic clocks. It helps keep cell phone networks, internet systems, and satellite navigation working with perfect time accuracy.
  • Physics laboratories: Researchers use special beams of light called a diode laser for laser cooling. This technique slows down rubidium atoms until they are nearly frozen still, helping physicists study the secrets of quantum physics.
  • Medicine and scanning: Doctors use a special isotope called Rubidium-82 in hospitals during positron emission tomography scans. This helps medical teams check blood flow in patients through safe medical imaging.
  • Special equipment: Small amounts of rubidium vapor are used inside sensitive sensors called magnetometers, which measure magnetic fields, and inside parts for older vacuum tubes.

How Living Things React to Rubidium

Rubidium is not a necessary nutrient for plants or animals. However, inside living creatures, a rubidium ion carries the exact same electrical charge as a potassium ion. Because they are so alike, living cells easily absorb rubidium by mistake.

A normal adult human carries about 0.36 grams of rubidium naturally inside their cells without any harm. However, pure rubidium metal remains extremely dangerous to touch. It catches fire quickly and can burn skin, meaning only trained scientists wearing safety gear should handle it!

See also

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