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Hexane
Hexane-2D-Skeletal.svg
Hexane-2D-B.png
Hexane-from-xtal-1999-at-an-angle-3D-balls.png
Hexane-3D-vdW.png
IUPAC name Hexane
Other names Sextane
Identifiers
CAS number 110-54-3
PubChem 8058
EC number 203-777-6
DrugBank DB02764
KEGG C11271
MeSH n-hexane
ChEBI CHEBI:29021
RTECS number MN9275000
SMILES CCCCCC
Beilstein Reference 1730733
Gmelin Reference 1985
Properties
Molecular formula
Molar mass 0 g mol-1
Appearance Colorless liquid
Odor Petrolic
Density 0.6606 g mL−1
Melting point
Boiling point
9.5 mg L−1
log P 3.764
Vapor pressure 17.60 kPa (at 20.0 °C)
kH 7.6 nmol Pa−1 kg−1
λmax 200 nm
−74.6·10−6 cm3/mol
Refractive index (nD) 1.375
Viscosity 0.3 mPa·s
Thermochemistry
Std enthalpy of
formation ΔfHo298
−199.4–−198.0 kJ mol−1
Std enthalpy of
combustion
ΔcHo298
−4180–−4140 kJ mol−1
Standard molar
entropy So298
296.06 J K−1 mol−1
Specific heat capacity, C 265.2 J K−1 mol−1
Hazards
Main hazards Reproductive toxicity – After aspiration, pulmonary oedema, pneumonitis, and death
NFPA 704

NFPA 704.svg

3
1
0
 
Explosive limits 1.2–7.7%
U.S. Permissible
exposure limit (PEL)
TWA 500 ppm (1800 mg/m3)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Hexane is a type of organic compound with the chemical formula C6H14. It belongs to a group of chemicals called alkanes, which are made up of only carbon and hydrogen atoms. Hexane has six carbon atoms linked together.

The word "hexane" can refer to any of five different forms of this compound. These forms are called structural isomers. This means they all have the same chemical formula (C6H14) but their atoms are arranged in different shapes. However, in IUPAC naming, "hexane" usually means the straight-chain form, without any branches.

Hexane is a colourless liquid and doesn't react easily with other chemicals. You can find a lot of hexane in gasoline.

What is Hexane?

Hexane is a simple hydrocarbon. This means it is a chemical compound made only of hydrogen and carbon atoms. It is part of the alkane family, which are hydrocarbons where all the carbon-carbon bonds are single bonds.

The most common form of hexane is called n-hexane. This is a straight chain of six carbon atoms, with hydrogen atoms attached to them.

How Hexane is Used

Hexane is often used as a solvent. A solvent is a liquid that can dissolve other substances. Because hexane is good at dissolving oils and greases, it's used in many ways:

  • It helps extract vegetable oils from seeds, like soybeans.
  • It's used in some types of glues and adhesives.
  • It can be found in cleaning products and degreasers.
  • It's also used in laboratories as a chemical reagent.

Properties of Hexane

Hexane is a clear liquid that doesn't have a strong smell, though some people describe it as having a "petrol-like" odor. It does not mix well with water.

Here are some of its key properties:

  • Appearance: A clear, colourless liquid.
  • Density: It is lighter than water, with a density of about 0.66 grams per milliliter.
  • Boiling Point: It boils at around 69 degrees Celsius (156 degrees Fahrenheit). This means it turns into a gas at this temperature.
  • Melting Point: It freezes at about -95 degrees Celsius (-139 degrees Fahrenheit).

Safety Information

Hexane is a flammable liquid, meaning it can easily catch fire. It is important to handle it with care. It should be kept away from heat, sparks, and open flames.

Breathing in too much hexane vapor can cause dizziness or headaches. It's important to use hexane in well-ventilated areas to avoid breathing in too much of it.

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