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Europium, 63Eu
Europium.jpg
Europium
Pronunciation /jʊəˈroʊpiəm/ ​(YOOR-oh-PEE-əm)
Appearance silvery white, with a pale yellow tint; but rarely seen without oxide discoloration
Standard atomic weight Ar, std(Eu) 151.964(1)
Europium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
–
↑
Eu
↓
Am
samarium ← europium → gadolinium
Atomic number (Z) 63
Group n/a
Period period 6
Block   f
Electron configuration [Xe] 4f7 6s2
Electrons per shell 2, 8, 18, 25, 8, 2
Physical properties
Phase at STP solid
Melting point 1099 K ​(826 °C, ​1519 °F)
Boiling point 1802 K ​(1529 °C, ​2784 °F)
Density when liquid (at m.p.) 5.13 g/cm3
Heat of fusion 9.21 kJ/mol
Heat of vaporization 176 kJ/mol
Molar heat capacity 27.66 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 863 957 1072 1234 1452 1796
Atomic properties
Oxidation states +1, +2, +3 (a mildly basic oxide)
Electronegativity Pauling scale: 1.2
Ionization energies
  • 1st: 547.1 kJ/mol
  • 2nd: 1085 kJ/mol
  • 3rd: 2404 kJ/mol
Atomic radius empirical: 180 pm
Covalent radius 198±6 pm
Color lines in a spectral range
Spectral lines of europium
Other properties
Natural occurrence primordial
Crystal structure ​body-centered cubic (bcc)
Body-centered cubic crystal structure for europium
Thermal conductivity est. 13.9 W/(m⋅K)
Electrical resistivity poly: 0.900 µΩ⋅m (at r.t.)
Magnetic ordering paramagnetic
Molar magnetic susceptibility +34000.0×10−6 cm3/mol
Young's modulus 18.2 GPa
Shear modulus 7.9 GPa
Bulk modulus 8.3 GPa
Poisson ratio 0.152
Vickers hardness 165–200 MPa
CAS Number 7440-53-1
History
Naming after Europe
Discovery Eugène-Anatole Demarçay (1896)
First isolation 1937
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct

Europium is a special chemical element. Its symbol is Eu, and its atomic number is 63. It belongs to a family of metals called the lanthanide group. Europium looks shiny and silvery-white when clean. It is one of the rarest of all the rare-earth elements found on Earth.

Amazing Physical and Chemical Features

Europium is a very soft rare-earth metal. It is ductile, which means you can bend it without breaking it. You can even cut pure europium with a simple kitchen knife. Its hardness is like soft lead. Inside its atoms, its electron configuration makes it act differently from its neighbors. Europium atoms arrange themselves into a body-centered cubic structure under normal room conditions.

Europium is the most active metal among the lanthanide elements. It is an electropositive metal that loves to join with other elements. When left in open air, it quickly reacts with oxygen to make europium(III) oxide. It also reacts with water to release hydrogen gas. Europium easily combines with every halogen element too. In water, it behaves like a hard Lewis acid. Chemists look at its two main forms, known as the +2 and +3 oxidation state levels. In the +2 form, it acts as a reducing agent because it gives away electrons.

Glowing Compounds of Europium

Crystals of europium sulfate
Europium glowing red under UV light
Europium sulfate in daylight and glowing red under UV light

Europium can build many kinds of compounds. Europium(II) oxide is a special semiconductor that can become ferromagnetic when cold. Another compound, called europium(III) chloride, can shine brightly under special lights.

Europium compounds are famous for their phosphorescence. When you shine ultraviolet light on them, they absorb the energy and glow. Some europium compounds use an antenna effect, where parts catch light energy and pass it along.

History of Discovery

Scientists discovered europium through long detective work. In 1803, chemists discovered cerium. Over time, they realized that other elements were hiding inside it. Scientist Carl Gustaf Mosander separated new parts, and later researchers found praseodymium and neodymium. In 1879, chemist Paul Émile Lecoq de Boisbaudran separated samarium. Later, he also found gadolinium.

In 1885, a scientist named William Crookes noticed an odd glow in test samples. Finally, in 1901, French chemist Eugène-Anatole Demarçay proved that europium was truly a brand-new element. He named it after the continent of Europe. Later, in 1937, scientists Wilhelm Klemm and Heinrich Bommer made the first pure metal pieces.

Where It Comes From and Everyday Uses

Europium never sits alone in nature. Miners dig it up inside rocks like bastnäsite, monazite, loparite-(Ce), and xenotime. Monazite can also contain thorium and yttrium. Huge mines, such as the Bayan Obo deposit, dig up these rare minerals.

Europium is used to make brilliant red light inside older colour television screens. It works as a bright phosphor inside energy-saving fluorescent lamps. Europium is also added to the paper money of the euro currency to prevent counterfeiting.

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See also

Kids robot.svg In Spanish: Europio para niños

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