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Cadmium, 48Cd
Cadmium-crystal bar.jpg
Cadmium
Pronunciation /ˈkædmiəm/ (KAD-mee-əm)
Appearance silvery bluish-gray metallic
Standard atomic weight Ar, std(Cd) 112.414(4)
Cadmium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Zn

Cd

Hg
silvercadmiumindium
Atomic number (Z) 48
Group group 12
Period period 5
Block   d
Electron configuration [Kr] 4d10 5s2
Electrons per shell 2, 8, 18, 18, 2
Physical properties
Phase at STP solid
Melting point 594.22 K ​(321.07 °C, ​609.93 °F)
Boiling point 1040 K ​(767 °C, ​1413 °F)
Density (near r.t.) 8.65 g/cm3
when liquid (at m.p.) 7.996 g/cm3
Heat of fusion 6.21 kJ/mol
Heat of vaporization 99.87 kJ/mol
Molar heat capacity 26.020 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 530 583 654 745 867 1040
Atomic properties
Oxidation states −2, +1, +2 (a mildly basic oxide)
Electronegativity Pauling scale: 1.69
Ionization energies
  • 1st: 867.8 kJ/mol
  • 2nd: 1631.4 kJ/mol
  • 3rd: 3616 kJ/mol
Atomic radius empirical: 151 pm
Covalent radius 144±9 pm
Van der Waals radius 158 pm
Color lines in a spectral range
Spectral lines of cadmium
Other properties
Natural occurrence primordial
Crystal structure ​hexagonal close-packed (hcp)
Hexagonal close packed crystal structure for cadmium
Speed of sound thin rod 2310 m/s (at 20 °C)
Thermal expansion 30.8 µm/(m⋅K) (at 25 °C)
Thermal conductivity 96.6 W/(m⋅K)
Electrical resistivity 72.7 nΩ⋅m (at 22 °C)
Magnetic ordering diamagnetic
Molar magnetic susceptibility −19.8·10−6 cm3/mol
Young's modulus 50 GPa
Shear modulus 19 GPa
Bulk modulus 42 GPa
Poisson ratio 0.30
Mohs hardness 2.0
Brinell hardness 203–220 MPa
CAS Number 7440-43-9
History
Discovery and first isolation Karl Samuel Leberecht Hermann and Friedrich Stromeyer (1817)
Named by Friedrich Stromeyer (1817)
Main isotopes of cadmium
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct
106Cd 1.25% stable
107Cd syn 6.5 h ε 107Ag
108Cd 0.89% stable
109Cd syn 462.6 d ε 109Ag
110Cd 12.47% stable
111Cd 12.80% stable
112Cd 24.11% stable
113Cd 12.23% 7.7×1015 y β 113In
113mCd syn 14.1 y β 113In
IT 113Cd
114Cd 28.75% stable
115Cd syn 53.46 h β 115In
116Cd 7.51% 3.1×1019 y ββ 116Sn

Cadmium is a special kind of metal. It's element number 48 on the periodic table, which is like a big chart of all known elements. Its short symbol is Cd. Cadmium is found in a group on the periodic table called Group 12.

What is Cadmium Like?

How it Looks and Feels (Physical Properties)

Cadmium is a soft metal that looks blue-gray. You can easily shape it or pull it into wires. This means it is malleable and ductile. It's a bit like zinc, another metal. Cadmium melts at 321 degrees Celsius (610 degrees Fahrenheit).

Cadmium has 8 natural forms called isotopes. Some of these isotopes are slightly radioactive, but most are not very active at all.

How it Reacts (Chemical Properties)

Cadmium is a metal that reacts moderately with other things. If it's in moist air, it can start to rust or corrode. It also dissolves if you put it in acids. If you grind cadmium into a powder and burn it in the air, it turns into a brown powder called cadmium oxide.

Cadmium Compounds

Cadmium chloride hemipentahydrate
Cadmium chloride
Oxid kademnatý
Cadmium oxide

Cadmium can join with other elements to form different chemical compounds. Most of the time, it forms compounds where it has a +2 charge. These compounds often dissolve easily in water. Many of them are white or yellow. For example, cadmium sulfide is a bright yellow color. Cadmium chloride and cadmium sulfate are clear solids that dissolve well in water.

History of Cadmium

Cadmium was first discovered in 1817 by a German chemist named Friedrich Stromeyer. Another chemist, Karl Herman, also found it in 1818. They found it while studying an impurity in zinc carbonate. For about 100 years, most of the world's cadmium came from Germany. In the past, Cadmium iodide was even used as a medicine, even though it was toxic.

Where is Cadmium Found?

Greenockite-Chalcopyrite-Prehnite-210604
Greenockite (yellow crystal)

Cadmium ores, which are rocks containing the metal, are quite rare. The main ore for cadmium is called Greenockite. This mineral is usually found alongside sphalerite, which is a zinc ore. Because of this, most of the cadmium we use today comes from processing zinc. Pure cadmium metal is very rare to find naturally, but it has been found in one place in Russia.

How is Cadmium Made?

Today, China makes the most cadmium in the world. South Korea and Japan also produce a lot of it. Cadmium is usually separated from zinc. One way is to heat zinc metal in a special container without air. Cadmium boils at a lower temperature than zinc, so it turns into a gas first. This gas is then cooled down to get pure cadmium. Another way is to separate it from the liquid solution used to make pure zinc through a process called electrolysis.

What is Cadmium Used For?

In the 1930s and 1940s, cadmium was mainly used to coat steel. This coating helped stop the steel from rusting. Later, cadmium sulfide was used as a bright yellow pigment in paints.

Today, the biggest use for cadmium is in nickel-cadmium batteries. As of 2009, about 86% of all cadmium was used in these batteries. Some people are trying to find other types of batteries because cadmium can be harmful. Cadmium is still used to coat steel to prevent rust, but this is a much smaller use now.

Cadmium is also used in other things like lasers, nuclear reactors, and special materials called phosphors that glow. It's also found in semiconductors, which are important parts of electronics. A special alloy (a mix of metals) called Wood's metal contains cadmium and melts very easily. Cadmium is also used in some types of solder, which is used to join metal parts.

Interestingly, while cadmium is not used by humans or most animals, a tiny ocean plant called a diatom actually uses cadmium.

Is Cadmium Safe?

Cadmium is a metal that can be very harmful. Breathing in dust from cadmium or its compounds can be dangerous. Because of its risks, some countries have banned cadmium from being used in electronics.

One of the main ways people are exposed to cadmium is through Cigarette smoking. People who smoke usually have about four times more cadmium in their blood than people who don't smoke. Scientists are still studying if cadmium directly causes cancer, or if other things found with it, like arsenic, are the cause.

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See also

Kids robot.svg In Spanish: Cadmio para niños

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