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Krypton, 36Kr
Krypton discharge tube.jpg
A krypton-filled discharge tube glowing white
Krypton
Pronunciation /ˈkrɪptɒn/ (KRIP-ton)
Appearance colorless gas, exhibiting a whitish glow in an electric field
Standard atomic weight Ar, std(Kr) 83.798(2)
Krypton in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Ar

Kr

Xe
brominekryptonrubidium
Atomic number (Z) 36
Group group 18 (noble gases)
Period period 4
Block   p
Electron configuration [Ar] 3d10 4s2 4p6
Electrons per shell 2, 8, 18, 8
Physical properties
Phase at STP gas
Melting point 115.78 K ​(−157.37 °C, ​−251.27 °F)
Boiling point 119.93 K ​(−153.415 °C, ​−244.147 °F)
Density (at STP) 3.749 g/L
when liquid (at b.p.) 2.413 g/cm3
Triple point 115.775 K, ​73.53 kPa
Critical point 209.48 K, 5.525 MPa
Heat of fusion 1.64 kJ/mol
Heat of vaporization 9.08 kJ/mol
Molar heat capacity 20.95  J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 59 65 74 84 99 120
Atomic properties
Oxidation states 0, +1, +2 (rarely more than 0; oxide is unknown)
Electronegativity Pauling scale: 3.00
Ionization energies
  • 1st: 1350.8 kJ/mol
  • 2nd: 2350.4 kJ/mol
  • 3rd: 3565 kJ/mol
Covalent radius 116±4 pm
Van der Waals radius 202 pm
Color lines in a spectral range
Spectral lines of krypton
Other properties
Natural occurrence primordial
Crystal structure face-centered cubic (fcc)
Face-centered cubic crystal structure for krypton
Speed of sound (gas, 20 °C) 221 m·s−1
(liquid) 1120 m/s
Thermal conductivity 9.43×10−3  W/(m⋅K)
Magnetic ordering diamagnetic
Molar magnetic susceptibility −28.8×10−6 cm3/mol (298 K)
CAS Number 7439-90-9
History
Naming from Greek κρυπτός, 'hidden'
Discovery and first isolation William Ramsay and Morris Travers (1898)
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct

Krypton is a fascinating chemical element. Its name comes from a Greek word meaning "the hidden one." Krypton has the symbol Kr and atomic number 36. It is a noble gas, which means it's a gas that doesn't usually react with other elements. You can't see or smell krypton because it's colorless and odorless.

Krypton is found in tiny amounts in the air around us. It's often used with other rare gases in special fluorescent lamps to create light. Like other noble gases, krypton is important in lighting and photography. The light from krypton has many different colors, called spectral lines.

Krypton gas can be used in powerful lasers. These lasers are used for many things, from light shows to scientific research. For a time, from 1960 to 1983, the official way to define a metre (a unit of length) was based on the specific color of light from a special type of krypton. This shows how stable and precise krypton's light is!

Discovering Krypton

William Ramsay working
Sir William Ramsay, who helped discover krypton.

Krypton was discovered in Britain in 1898. Two clever chemists, William Ramsay from Scotland and Morris Travers from England, found it. They discovered krypton while studying what was left after almost all parts of liquid air had evaporated. Just a few weeks later, they found another noble gas, Neon, using a similar method.

William Ramsay received the Nobel Prize in Chemistry in 1904. He was honored for discovering a group of these special noble gases, including krypton.

In 1960, scientists used krypton to define the metre. They said one meter was equal to 1,650,763.73 wavelengths of a specific light color from krypton-86. This was a very precise way to measure length. This definition was used until October 1983. Then, scientists changed the definition of the meter to be based on how far light travels in a vacuum in a tiny fraction of a second.

How Krypton Behaves

Krypton creates several bright colors of light when it's excited. The strongest colors are green and yellow. Solid krypton is white and has a common crystal structure that looks like a cube. This is true for most noble gases.

Different Forms: Krypton Isotopes

Elements can have different versions called isotopes. These isotopes have the same number of protons but different numbers of neutrons. Naturally, krypton in Earth's atmosphere has five stable isotopes. There's also one isotope, 78Kr, that lasts so long it's considered stable.

Scientists know about many other unstable isotopes of krypton. One of these, 81Kr, is made when cosmic rays hit 80Kr. This isotope is radioactive and has a half-life of 230,000 years. This means it takes 230,000 years for half of it to change into something else. 81Kr is useful for dating very old groundwater, helping scientists understand water sources from 50,000 to 800,000 years ago.

Another isotope, 85Kr, is also radioactive with a half-life of about 10.76 years. It is created during certain human activities involving nuclear energy. Scientists can use 85Kr in the atmosphere to detect specific industrial activities. For example, in the early 2000s, it helped identify facilities that were processing nuclear materials.

Krypton's Chemical Side

Krypton is known for being very unreactive. This means it doesn't easily combine with other elements to form new substances. For a long time, scientists thought noble gases couldn't form any compounds at all.

However, in the 1960s, scientists learned how to make some noble gases react. They successfully created a compound called krypton difluoride (KrF2) by making krypton react with fluorine under very special conditions.

Krypton fluoride is also used in a special type of laser. In these lasers, krypton gas reacts with fluorine gas to create a temporary compound. This compound then releases energy as light, which is used in the laser.

Scientists have even found compounds where krypton is bonded to atoms other than fluorine, like oxygen and nitrogen. They have also created special krypton hydride crystals under very high pressures.

Where is Krypton Found?

Krypton is present in the air at a very low concentration, about one ppm. This means for every million particles of air, only one is krypton. Scientists can get krypton from liquid air using a process called fractional distillation.

The amount of krypton in space is harder to measure. However, early measurements suggest that krypton is also found in space.

Amazing Uses of Krypton

KrTube
Krypton gas discharge tube, showing its light.

Krypton's ability to produce a whitish light when ionized makes it useful in photography. It's used in some camera flashes for high-speed photos. Krypton gas can also be mixed with mercury to create bright greenish-blue light in luminous signs.

Krypton is added to argon in some energy-efficient fluorescent lamps. This helps reduce how much power the lamps use. It's also used in regular light bulbs (incandescent lamps) to help the filament last longer and burn brighter.

The white light from krypton is sometimes used for artistic effects in "neon" tubes. Krypton lasers can produce powerful red light, which is great for laser light shows.

In scientific research, a krypton fluoride laser is important for studying nuclear fusion energy. This laser can create a very uniform beam of light.

Liquid krypton is used in experimental particle physics to build special detectors called calorimeters. These detectors help scientists study tiny particles. For example, a large detector at CERN used about 27 tons of liquid krypton.

Krypton also has medical uses. A special isotope, Krypton-83, is used in magnetic resonance imaging (MRI) to create images of airways in the lungs. This helps doctors see the surfaces inside the lungs. Another isotope, krypton-81m, is used in nuclear medicine for lung scans. Patients inhale it, and a special camera takes pictures of their lungs.

Krypton is sometimes used as an insulating gas between window panes to improve energy efficiency. Even in space, krypton has a role! SpaceX uses krypton as a fuel for the electric propulsion systems on their Starlink satellites.

Staying Safe with Krypton

The Meyer-Overton correlation
This chart compares krypton to other gases that can cause sleepiness.

Krypton is not poisonous, but it is an asphyxiant. This means that if there's too much krypton in the air, it can reduce the amount of oxygen you breathe. Breathing air with too little oxygen can make you feel dizzy or even pass out.

Krypton can also make you feel sleepy or dizzy, similar to how you might feel if you were deep-sea diving. If someone were to breathe air that is 50% krypton, it would feel like breathing air at four times the normal atmospheric pressure. This effect is like scuba diving about 30 meters (100 feet) deep. It's important to be careful around krypton gas to ensure there's always enough oxygen in the air.


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See also

Kids robot.svg In Spanish: Kriptón para niños

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