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Lithium, 3Li
Lithium paraffin.jpg
Lithium floating in oil
Lithium
Pronunciation /ˈlɪθiəm/ (LITH-ee-əm)
Appearance silvery-white
Standard atomic weight Ar, std(Li) [6.9386.997] conventional: 6.94
Lithium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
H

Li

Na
heliumlithiumberyllium
Atomic number (Z) 3
Group group 1: hydrogen and alkali metals
Period period 2
Block   s
Electron configuration [He] 2s1
Electrons per shell 2, 1
Physical properties
Phase at STP solid
Melting point 453.65 K ​(180.50 °C, ​356.90 °F)
Boiling point 1603 K ​(1330 °C, ​2426 °F)
Density (near r.t.) 0.534 g/cm3
when liquid (at m.p.) 0.512 g/cm3
Critical point 3220 K, 67 MPa (extrapolated)
Heat of fusion 3.00 kJ/mol
Heat of vaporization 136 kJ/mol
Molar heat capacity 24.860 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 797 885 995 1144 1337 1610
Atomic properties
Oxidation states +1 (a strongly basic oxide)
Electronegativity Pauling scale: 0.98
Ionization energies
  • 1st: 520.2 kJ/mol
  • 2nd: 7298.1 kJ/mol
  • 3rd: 11815.0 kJ/mol
Atomic radius empirical: 152 pm
Covalent radius 128±7 pm
Van der Waals radius 182 pm
Color lines in a spectral range
Spectral lines of lithium
Other properties
Natural occurrence primordial
Crystal structure body-centered cubic (bcc)
Body-centered cubic crystal structure for lithium
Speed of sound thin rod 6000 m/s (at 20 °C)
Thermal expansion 46 µm/(m⋅K) (at 25 °C)
Thermal conductivity 84.8 W/(m⋅K)
Electrical resistivity 92.8 nΩ⋅m (at 20 °C)
Magnetic ordering paramagnetic
Molar magnetic susceptibility +14.2·10−6 cm3/mol (298 K)
Young's modulus 4.9 GPa
Shear modulus 4.2 GPa
Bulk modulus 11 GPa
Mohs hardness 0.6
Brinell hardness 5 MPa
CAS Number 7439-93-2
History
Discovery Johan August Arfwedson (1817)
First isolation William Thomas Brande (1821)
Main isotopes of lithium
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct
6Li 5% stable
7Li 95% stable
6Li content may be as low as 3.75% in
natural samples. 7Li would therefore
have a content of up to 96.25%.

Lithium is a soft, shiny silver-white metal. Its name comes from the Greek word lithos, meaning 'stone'. You can find it on the periodic table with the symbol Li.

Lithium is the third chemical element, which means it has 3 protons in its center (called the nucleus) and 3 electrons orbiting around it. Its atomic number is 3. Lithium is very reactive, meaning it easily combines with other substances. It's used in many things, like batteries and some medicines.

What is Lithium Like?

Physical Features of Lithium

Lithium is part of a group called alkali metals. When you cut it, it looks silvery and shiny. It's so soft you can easily cut it with a knife! Lithium melts at a low temperature. It's also super light, almost like wood. In fact, it's the lightest metal and the lightest element when it's a solid or liquid. Lithium is good at holding heat and lets electricity pass through it easily.

How Lithium Reacts (Chemical Properties)

Lithium loves to react with water. When it touches water, it creates hydrogen gas and a basic solution called lithium hydroxide. Because it reacts with water, lithium must be kept safe in petroleum jelly. Other similar metals like sodium and potassium can be stored in oil, but lithium is too light and would just float on top!

Lithium also reacts with halogens (like chlorine) and even nitrogen gas to form lithium nitride. If lithium touches air, it gets a black coating, which then turns into a white powder made of lithium hydroxide and lithium carbonate.

Lithium Compounds: What They Make

FlammenfärbungLi
See the bright red color lithium makes in a flame test!

Lithium forms chemical compounds where it has a +1 oxidation state. Most of these compounds are white and don't react much. When you heat them in a flame, they glow a bright red color. They can be a little bit harmful, but most of them dissolve in water. Lithium carbonate doesn't dissolve as easily in water as some other similar compounds.

Here are some important lithium compounds:

Where is Lithium Found?

You won't find pure lithium metal in nature. It's always found as part of chemical compounds. The ocean contains a lot of lithium. Some types of granite rock also have a lot of it. Most living things, including us, have small amounts of lithium. It's also found in salty areas and in some silicate rocks.

History of Lithium

Lithium was found by Johann Arfvedson in 1817. In 1818, Christian Gmelin noticed that lithium salts made a bright red color when burned in a flame. Later, W.T. Brande and Sir Humphry Davy used electrolysis (using electricity to separate chemicals) on lithium oxide to get pure lithium metal.

At first, lithium was used in greases. Then, it became important for certain weapons. It was also used to help glass and aluminium oxide melt more easily. Today, lithium is mostly used in batteries. It was named "lithium" because it was discovered from a mineral (a "stone"), while other similar metals were first found in plants.

How Lithium is Made

Lithium is made by taking lithium chloride from natural pools and springs. This lithium chloride is then melted and put through electrolysis. This process separates it into liquid lithium metal and chlorine gas.

Uses of Lithium

Lithium as an Element

The main use for lithium metal is in batteries. It acts as an anode (a part that helps electricity flow) in lithium batteries. These batteries are more powerful than ones made with zinc. Lithium-ion batteries also use lithium, but not as a pure element.

Lithium is also used in special metal mixtures called alloys that transfer heat well. It helps make organolithium compounds, which are very strong bases used in chemistry.

Because lithium is the lightest known metal, it can be mixed with other metals like aluminium, copper, and cadmium. These mixtures create strong, lightweight metals perfect for aircraft.

Lithium in Compounds

Lithium compounds are used in some drugs called mood stabilizers. These help people with certain mental health conditions. Lithium niobate is used in radio transmitters found in cell phones. Some lithium compounds are also used to make ceramics.

Lithium chloride can absorb water from other things, making it useful as a drying agent. Some lithium compounds are also used to make soap and grease. Lithium carbonate is a medicine used to treat bipolar disorder and other mental illnesses.

Lithium in Organic Chemistry

Organolithium compounds are used to make polymers (large molecules) and fine chemicals (specialized chemicals). Many lithium compounds act as reagents (substances that cause chemical reactions) to create organic compounds. Some, like lithium aluminium hydride, are very strong bases called superbases.

Other Uses for Lithium

Lithium compounds are used to create the red color in fireworks and flares. Lithium chloride and lithium bromide are used as desiccants to dry out gas streams.

Lithium hydroxide and lithium peroxide are used to remove carbon dioxide and clean the air in spacecrafts and submarines. These compounds are also found in "oxygen candles" that provide oxygen to submarines.

Lithium aluminum hydride can be used as a solid fuel. A special type of lithium hydride containing lithium-6 was used in some powerful weapons.

Safety with Lithium

Lithium reacts with water, creating irritating smoke and heat. While it's not as dangerous as some other alkali metals, it still needs to be handled carefully. Lithium hydroxide is a very strong chemical that can cause burns.

Lithium's Isotopes

Lithium has five different isotopes. Isotopes are versions of an element that have the same number of protons but different numbers of neutrons in their nucleus. The most common isotope of Lithium in nature is 3Li7, which makes up about 92.58% of all lithium. The next most common is 3Li6, making up 7.42%. The other three isotopes are very rare. The average atomic mass of Lithium is 6.939.

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