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Tin, 50Sn
Sn-Alpha-Beta.jpg
Tin
Allotropes silvery-white, β (beta); gray, α (alpha)
Appearance silvery-white (beta, β) or gray (alpha, α)
Standard atomic weight Ar, std(Sn) 118.710(7)
Tin in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Ge

Sn

Pb
indiumtinantimony
Atomic number (Z) 50
Group group 14 (carbon group)
Period period 5
Block   p
Electron configuration [Kr] 4d10 5s2 5p2
Electrons per shell 2, 8, 18, 18, 4
Physical properties
Phase at STP solid
Melting point 505.08 K ​(231.93 °C, ​449.47 °F)
Boiling point 2875 K ​(2602 °C, ​4716 °F)
Density (near r.t.) white, β: 7.265 g/cm3
gray, α: 5.769 g/cm3
when liquid (at m.p.) 6.99 g/cm3
Heat of fusion white, β: 7.03 kJ/mol
Heat of vaporization white, β: 296.1 kJ/mol
Molar heat capacity white, β: 27.112 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 1497 1657 1855 2107 2438 2893
Atomic properties
Oxidation states −4, −3, −2, −1, +1, +2, +3, +4 (an amphoteric oxide)
Electronegativity Pauling scale: 1.96
Ionization energies
  • 1st: 708.6 kJ/mol
  • 2nd: 1411.8 kJ/mol
  • 3rd: 2943.0 kJ/mol
Atomic radius empirical: 140 pm
Covalent radius 139±4 pm
Van der Waals radius 217 pm
Color lines in a spectral range
Spectral lines of tin
Other properties
Natural occurrence primordial
Crystal structure ​tetragonal
Tetragonal crystal structure for tin

white (β)
Crystal structure ​face-centered diamond-cubic
Diamond cubic crystal structure for tin

gray (α)
Speed of sound thin rod 2730 m/s (at r.t.) (rolled)
Thermal expansion 22.0 µm/(m⋅K) (at 25 °C)
Thermal conductivity 66.8 W/(m⋅K)
Electrical resistivity 115 nΩ⋅m (at 0 °C)
Magnetic ordering gray: diamagnetic
white (β): paramagnetic
Molar magnetic susceptibility (white) +3.1·10−6 cm3/mol (298 K)
Young's modulus 50 GPa
Shear modulus 18 GPa
Bulk modulus 58 GPa
Poisson ratio 0.36
Brinell hardness 50–440 MPa
CAS Number 7440-31-5
History
Discovery around 3500 BC
Symbol "Sn": from Latin stannum
Main isotopes of tin
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct
112Sn 0.97% stable
114Sn 0.66% stable
115Sn 0.34% stable
116Sn 14.54% stable
117Sn 7.68% stable
118Sn 24.22% stable
119Sn 8.59% stable
120Sn 32.58% stable
122Sn 4.63% stable
124Sn 5.79% stable
126Sn trace 2.3×105 y β 126Sb

Tin is a chemical element with the symbol Sn and atomic number 50. The symbol Sn comes from its Latin name, stannum. Tin is a silvery-gray metal that is so soft you can cut it with little force. You can even bend a bar of tin by hand.

When you bend a piece of tin, it makes a strange cracking sound called the "tin cry." This sound comes from the tiny crystals inside the metal rubbing against each other as they move.

Tin is a post-transition metal in group 14 of the periodic table. It is found in nature mainly in a mineral called cassiterite. Tin is similar to its neighbors on the periodic table, germanium and lead. It is the 49th most common element in the Earth's crust.

One of the first important uses for tin was to make bronze, a strong metal alloy made by mixing tin with copper. Today, tin is used for many things, from coating steel cans to protect food, to making the solder that holds electronic circuits together.

Characteristics

Physical Properties

Tin-2
A droplet of melted tin that has cooled and become solid.

Tin is a soft, silvery-white metal that can be easily shaped without breaking. This property is called being malleable. As mentioned before, it makes a unique "tin cry" sound when bent. This is a special trait it shares with a few other metals like indium and cadmium.

Tin has a low melting point for a metal, at about 232 °C (450 °F). This makes it easy to melt and mix with other metals to form alloys.

Two Forms of Tin

Tin can exist in two main forms, called allotropes.

  • β-tin (Beta-tin), or white tin, is the normal metallic form we see at room temperature. It is shiny and easy to work with.
  • α-tin (Alpha-tin), or gray tin, is a non-metallic powder. This form appears when tin gets very cold, below 13.2 °C (55.8 °F).

When white tin gets too cold, it can slowly turn into gray tin powder. This change is called "tin pest" or "tin disease" because it can cause tin objects to crumble and fall apart. There is a legend that during Napoleon's invasion of Russia in 1812, the extreme cold caused the tin buttons on his soldiers' uniforms to crumble away, which added to their problems.

To prevent tin pest, small amounts of other metals like antimony or bismuth are often added to tin. This makes the tin stronger and more durable, especially in the cold.

A Special Element: Isotopes

Isotopes are different versions of an element's atom that have a different number of neutrons. Tin is special because it has ten stable isotopes, which is more than any other element in the periodic table.

Scientists believe this is because tin's atomic number is 50. In nuclear physics, 50 is a "magic number" of protons, which makes the atom's nucleus unusually stable.

History of Tin

Sword bronze age (2nd version)
A ceremonial bronze sword from the Bronze Age, made around 1500–1300 BC.

People started using tin around 3000 BC, at the beginning of the Bronze Age. Early metalworkers discovered that if they mixed a small amount of tin (about 12%) with copper, they could create a new metal called bronze.

Bronze was much harder and stronger than pure copper. It was also easier to melt and cast into complex shapes like tools, weapons, and armor. This discovery was a major step forward for human technology.

Since tin was not very common, a large trade network was created to bring tin from faraway mines to the civilizations that needed it.

Later, after 600 BC, people learned how to produce pure tin. Another important tin alloy is pewter, which is about 90% tin. Pewter was used for centuries to make plates, cups, and other tableware because it was easy to shape and didn't rust.

Where is Tin Found?

Cassiterite09
A sample of cassiterite, the main ore that tin comes from.

Tin is not found as a pure metal in nature. It is extracted from ores, with the most important one being cassiterite (tin oxide, SnO2). Cassiterite is a hard, heavy mineral that is often found in or near granite rock.

Over millions of years, wind and rain wear down the rock, and the heavy cassiterite gets washed into rivers and streams. It settles on the riverbeds in deposits called placer deposits. About 80% of the world's tin is mined from these deposits.

Today, the largest tin-producing countries are China, Indonesia, Peru, Bolivia, and Brazil.

What is Tin Used For?

TinConsChart
A chart showing the main uses of tin around the world in 2006.

Tin is a very useful metal with many modern applications. In 2018, almost half of all tin was used to make solder.

Solder

Ex Lead freesolder
A roll of lead-free solder wire, used for electronics.

Solder is a metal alloy that is melted to join metal pieces together, like a type of metal glue. For a long time, solder was made from tin and lead. It is essential for making electric circuits, as it connects all the tiny components on a circuit board.

Because lead can be harmful to people's health and the environment, most countries now require lead-free solder. Modern lead-free solders are usually made of mostly tin, with small amounts of copper and silver.

Tin Plating and Cans

Inside of a tin platted can
The inside of a food can, showing the shiny tin plating that protects the steel.

Tin is excellent at preventing rust. Because of this, it is often used to coat other metals like steel. The "tin cans" we use for food are actually steel cans with a very thin layer of tin on the inside and outside. This tin plating protects the steel from rusting and keeps the food inside safe to eat.

Copper pots and pans are also often lined with tin. This is because copper can react with acidic foods, but the tin lining creates a safe barrier.

Important Alloys

An alloy is a mixture of two or more metals. Tin is a key ingredient in several important alloys.

  • Bronze is an alloy of copper and tin. It is used to make statues, bells, and medals.
  • Pewter is an alloy that is mostly tin, with small amounts of copper and antimony. It is used to make decorative items like plates, mugs, and figurines.
  • Babbitt metal is a soft alloy of tin used to make bearings for machines, helping parts move smoothly with little friction.

Other Cool Uses

Plate MET 174927
A decorative plate made of pewter.
  • Making Glass: Most of the flat window glass we use today is made using a method called the Pilkington process. In this process, melted glass is floated on top of a large pool of molten tin. Because the tin is perfectly flat, the glass cools into a smooth, flawless sheet.
  • Touch Screens: A compound called Indium tin oxide is both transparent and electrically conductive. It is used to make the clear touch screens on smartphones, tablets, and TVs.
  • Toothpaste: Some toothpastes contain a compound called stannous fluoride. It helps fight cavities and prevent gum problems like gingivitis.

Safety

Tin metal is considered safe for humans to handle. This is why it has been used for centuries in food containers and kitchenware.

However, some special man-made tin compounds, known as organotin compounds, can be harmful if not handled properly. These chemicals were once used in paint for ships to stop barnacles from growing on them. But scientists discovered they were harming sea life, so their use is now heavily restricted around the world. People who work with these chemicals follow strict safety rules to protect themselves and the environment.

See also

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